新型炭材料
新型炭材料
신형탄재료
NEW CARBON MATERIALS
2012年
4期
241-249
,共9页
周绍鑫%祝渊%杜鸿达%李宝华%康飞宇
週紹鑫%祝淵%杜鴻達%李寶華%康飛宇
주소흠%축연%두홍체%리보화%강비우
天然鳞片石墨%流延法%定向排列%热导率
天然鱗片石墨%流延法%定嚮排列%熱導率
천연린편석묵%류연법%정향배렬%열도솔
Natural crystalline flake graphite%Tape casting%Orientation%Thermal conductivity
以天然鳞片石墨为原料,PVB为黏结剂,PEG和DBP混合物为增塑剂,通过流延工艺在室温下制备了定向排列的石墨/聚合物片层复合材料.系统分析了不同黏结剂用量和流延刀口高度下复合片层材料的定向排列状况,并探讨了定向排列程度对其热导率的影响.XRD和SEM的结果表明,石墨/聚合物复合片层材料显示了不同程度的定向排列.热导率测试结果表明,片层复合材料的热导率随着定向排列程度的提高而增大.通过优化黏结剂的用量和流延刀口高度制备了具有较高热导率的片层复合材料,其热导率最高可达490 W/(m·K).
以天然鱗片石墨為原料,PVB為黏結劑,PEG和DBP混閤物為增塑劑,通過流延工藝在室溫下製備瞭定嚮排列的石墨/聚閤物片層複閤材料.繫統分析瞭不同黏結劑用量和流延刀口高度下複閤片層材料的定嚮排列狀況,併探討瞭定嚮排列程度對其熱導率的影響.XRD和SEM的結果錶明,石墨/聚閤物複閤片層材料顯示瞭不同程度的定嚮排列.熱導率測試結果錶明,片層複閤材料的熱導率隨著定嚮排列程度的提高而增大.通過優化黏結劑的用量和流延刀口高度製備瞭具有較高熱導率的片層複閤材料,其熱導率最高可達490 W/(m·K).
이천연린편석묵위원료,PVB위점결제,PEG화DBP혼합물위증소제,통과류연공예재실온하제비료정향배렬적석묵/취합물편층복합재료.계통분석료불동점결제용량화류연도구고도하복합편층재료적정향배렬상황,병탐토료정향배렬정도대기열도솔적영향.XRD화SEM적결과표명,석묵/취합물복합편층재료현시료불동정도적정향배렬.열도솔측시결과표명,편층복합재료적열도솔수착정향배렬정도적제고이증대.통과우화점결제적용량화류연도구고도제비료구유교고열도솔적편층복합재료,기열도솔최고가체490 W/(m·K).
Oriented graphite/polymer composite sheets were prepared using natural,crystalline flake graphites as raw materials,polyvinyl butyral as binders,polyethylene glycol and dibutyl phthalate as plasticizers by a tape-casting method at room temperature.The dependences of the binder contents and the blade heights on the orientation of the composite sheets were studied,and the effect of the orientation on the thermal conductivity was investigated.X-ray diffraction patterns and scanning electron microscope images showed that as-prepared samples showed different degrees of orientation.The thermal conductivity increased with the degree of orientation.The highest thermal conductivity of 490 W/( m· K) could be achieved by optimizing the binder contents and the blade heights.