腐蚀科学与防护技术
腐蝕科學與防護技術
부식과학여방호기술
CORROSION SCIENCE AND PROTECTION TECHNOLOGY
2009年
4期
406-409
,共4页
陈云%唐永明%杨文忠%刘瑛%王锦堂
陳雲%唐永明%楊文忠%劉瑛%王錦堂
진운%당영명%양문충%류영%왕금당
缓蚀剂%紫铜%极化曲线%交流阻抗
緩蝕劑%紫銅%極化麯線%交流阻抗
완식제%자동%겁화곡선%교류조항
inhibitor%copper%polarization curves%electrochemical impedance
采用动电位极化曲线和电化学阻抗谱技术研究了3,5-二(2-噻吩基)-1,2,4-三唑(2-TAT)在1mol/LHCl介质中对紫铜的缓蚀作用.结果表明,2-TAT为阴极型缓蚀剂,阻抗参数的变化表明2-TAT吸附在紫铜表面,形成保护膜,其吸附方式遵循Langmuir吸附等温式.
採用動電位極化麯線和電化學阻抗譜技術研究瞭3,5-二(2-噻吩基)-1,2,4-三唑(2-TAT)在1mol/LHCl介質中對紫銅的緩蝕作用.結果錶明,2-TAT為陰極型緩蝕劑,阻抗參數的變化錶明2-TAT吸附在紫銅錶麵,形成保護膜,其吸附方式遵循Langmuir吸附等溫式.
채용동전위겁화곡선화전화학조항보기술연구료3,5-이(2-새분기)-1,2,4-삼서(2-TAT)재1mol/LHCl개질중대자동적완식작용.결과표명,2-TAT위음겁형완식제,조항삼수적변화표명2-TAT흡부재자동표면,형성보호막,기흡부방식준순Langmuir흡부등온식.
The effect of 3,5-bis (2-thienyl) -4-amino-1, 2,4-triazole (2-TAT) on corrosion inhibition of copper was studied in 1 molL-1 HC1 by polarization curves and electrochemical impedance spectroscopy. The electrochemical study reveals that the compound is a cathodic-type inhibitor. Changes in impedance parameters are the indication of adsorption of 2-TAT on the copper surface,leading to the formation of a protective film. The adsorption of 2-TAT obeys the Langmuir adsorption isotherm.