稀有金属材料与工程
稀有金屬材料與工程
희유금속재료여공정
RARE METAL MATERIALS AND ENGINEERNG
2009年
5期
770-773
,共4页
肖锋%杨仁辉%刘兰霄%赵红凯%方亮%张弛
肖鋒%楊仁輝%劉蘭霄%趙紅凱%方亮%張弛
초봉%양인휘%류란소%조홍개%방량%장이
商用镍基合金%密度%静滴法%摩尔体积
商用鎳基閤金%密度%靜滴法%摩爾體積
상용얼기합금%밀도%정적법%마이체적
Ni-based commercial alloys%density%sessile drop method%molar volume
采用改良静滴法测量并通过软件的计算得到了4种商用镍基合金的密度.结果表明,随着温度的升高,4种液态镍基合金的密度逐渐减小,摩尔体积逐渐增大.与理想混合状态相比,液体镍基合金的摩尔体积出现负偏差.从而可以推测在合金中各种原子之间发生了调整.
採用改良靜滴法測量併通過軟件的計算得到瞭4種商用鎳基閤金的密度.結果錶明,隨著溫度的升高,4種液態鎳基閤金的密度逐漸減小,摩爾體積逐漸增大.與理想混閤狀態相比,液體鎳基閤金的摩爾體積齣現負偏差.從而可以推測在閤金中各種原子之間髮生瞭調整.
채용개량정적법측량병통과연건적계산득도료4충상용얼기합금적밀도.결과표명,수착온도적승고,4충액태얼기합금적밀도축점감소,마이체적축점증대.여이상혼합상태상비,액체얼기합금적마이체적출현부편차.종이가이추측재합금중각충원자지간발생료조정.
The densities of four kinds of molten Ni-based commercial alloys were measured with a modified sessile drop method, and calculated using the calculating software. It is found that the densities of the molten Ni-based commercial alloys decrease and their molar volume increase with increasing of temperature. Compared with the ideal mixing, the molar volumes of the molten Ni-based commercial alloys show negative deviations. It can be attributed to an accommodation between various atoms in the alloys.