CAJ | 학술논문

原子转移自由基聚合(ATRP)技术是一种新型的可控/活性聚合技术,可有效地对聚合物的分子结构进行设计,制备出各种不同性能、不同组成、不同功能化的结构确定的聚合物.综述了利用ATRP技术合成树枝状一线性嵌段共聚物、类树枝状聚合物(dendrimer-like polymer)、具有刺激-响应性末端基团的树枝状聚合物、树枝状-星型嵌段共聚物和基于树枝状聚合物的聚合物刷的研究进展.
원자전이자유기취합(ATRP)기술시일충신형적가공/활성취합기술,가유효지대취합물적분자결구진행설계,제비출각충불동성능、불동조성、불동공능화적결구학정적취합물.종술료이용ATRP기술합성수지상일선성감단공취물、류수지상취합물(dendrimer-like polymer)、구유자격-향응성말단기단적수지상취합물、수지상-성형감단공취물화기우수지상취합물적취합물쇄적연구진전.
Atom transfer radical polymerization(ATRP)is one of.the new techniques employed in living/controlled radical polymerization.It is effective in the design of molecular structure of polymers.A variety of well defined polymers with different properties,composition and functions can be prepared by ATRP.The recent progress of ATRP applied to the synthesis of linear-dendritic block copolymers,dendrimer-like polymers,dendrimer-star polymers,dendrimers with stimulative response end group and dendrimer-based polymer molecular brushes is reviewed.