CAJ | 학술논문

为寻求更好的苯基卟啉类光电材料,以吡咯和取代苯甲醛为原料,通过改进的Alder法合成了3种苯基卟啉衍生物及其锌、锰配合物,对目标化合物进行了FT-IR、MS、XPS和元素分析等表征,并测试了化合物的紫外、荧光光谱,探讨了其光物理性能和电化学性质.结果表明：通过改进的合成方法,苯基卟啉衍生物及其锌、锰配合物合成简单、收率高且其光电性能良好.
위심구경호적분기계람류광전재료,이필각화취대분갑철위원료,통과개진적Alder법합성료3충분기계람연생물급기자、맹배합물,대목표화합물진행료FT-IR、MS、XPS화원소분석등표정,병측시료화합물적자외、형광광보,탐토료기광물이성능화전화학성질.결과표명：통과개진적합성방법,분기계람연생물급기자、맹배합물합성간단、수솔고차기광전성능량호.
With the intention to obtain highly efficient optic-electronic materials,three phenylporphyrin derivatives and their zinc,manganese complexes were synthesized by an improved Alder methods using pyrrole and substituted benzaldehydes as raw materials.The structures of these compounds were characterized by FT-IR,MS,XPS and element analysis,and their electronic absorption,fluorescence and eletrochemical properties have been systematically investigated.The phenylporphyrin derivatives and their zinc,manganese complexes can be simply synthesized with high yield using the improved methods.The target compounds have good optic-electronic properties.