质量技术监督研究
質量技術鑑督研究
질량기술감독연구
QUALITY AND TECHNICAL SUPERVISION RESEARCH
2011年
6期
9-12
,共4页
测试%纺织助染剂%氯化甲苯%气质联用
測試%紡織助染劑%氯化甲苯%氣質聯用
측시%방직조염제%록화갑분%기질련용
Determination%Textile auxiliary%Chlorinated toluene%GC-MS
本文建立了水溶性纺织助染剂中12种氯化甲苯化合物的气相色谱-质谱（GC-MS）测定方法。采用超声萃取法,以正己烷为溶剂分两次提取待测物,用DB-17MS为检测色谱柱气质联用法程序升温方式进行测定,外标法定量。结果表明该方法对12种氯化甲苯化合物的回收率为81.9%～105.6%,方法检测限可达9.8～21.6？g/kg。该法检测限低,准确可靠,适用于水溶性纺织助染剂中氯化甲苯化合物的分析监测。
本文建立瞭水溶性紡織助染劑中12種氯化甲苯化閤物的氣相色譜-質譜（GC-MS）測定方法。採用超聲萃取法,以正己烷為溶劑分兩次提取待測物,用DB-17MS為檢測色譜柱氣質聯用法程序升溫方式進行測定,外標法定量。結果錶明該方法對12種氯化甲苯化閤物的迴收率為81.9%～105.6%,方法檢測限可達9.8～21.6？g/kg。該法檢測限低,準確可靠,適用于水溶性紡織助染劑中氯化甲苯化閤物的分析鑑測。
본문건립료수용성방직조염제중12충록화갑분화합물적기상색보-질보（GC-MS）측정방법。채용초성췌취법,이정기완위용제분량차제취대측물,용DB-17MS위검측색보주기질련용법정서승온방식진행측정,외표법정량。결과표명해방법대12충록화갑분화합물적회수솔위81.9%～105.6%,방법검측한가체9.8～21.6？g/kg。해법검측한저,준학가고,괄용우수용성방직조염제중록화갑분화합물적분석감측。
A testing method for determination of twelve chlorinated toluenes in water-soluble textile dyeing auxiliary with GC-MS was established. With ultrasonic-assisted the sample was extracted twice by n-hexane.Then the extract was analyzed with DB-17MS by the temperature programming mode of GC-MS and was tested by external standard method. The results showed that with this method satisfactory recoveries 81.9%～105.6% and method detection limits 9.8～21.6 ＊g/kg could be obtained. The method features low detection limits and good accuracy, and could be used for handling water-soluble textile dyeing auxiliary samples.
