CAJ | 학술논문

介绍了用路易斯酸作催化剂，乙酸和乙醇进行酯化反应制乙酸乙酯的方法，该方法可获得高产率。探讨了该反应可能的催化机理和反应温度、不同催化剂、反应时间等对产品收率的影响，获得最佳反应条件为：催化剂用AlCl3，n(C2H5OH)∶n(CH3COOH)∶n(AlCl3)=2∶1∶0.03，反应温度90 ℃，反应时间45 min，由此产品收率可达94.3%。
개소료용로역사산작최화제，을산화을순진행지화반응제을산을지적방법，해방법가획득고산솔。탐토료해반응가능적최화궤리화반응온도、불동최화제、반응시간등대산품수솔적영향，획득최가반응조건위：최화제용AlCl3，n(C2H5OH)∶n(CH3COOH)∶n(AlCl3)=2∶1∶0.03，반응온도90 ℃，반응시간45 min，유차산품수솔가체94.3%。
The preparation method of acetic ester by esterification of acetic acid and ethanol using Lewis acid as catalyst was introduced and a possible reaction mechanism was discussed. The effects of reaction temperature, different Lewis acid catalysts, and reaction time on the yield were investigated. Optimum reaction condition was gained as follows: catalyst was aluminium chloride, ethanol∶acetic acid∶aluminium chloride was 2∶1∶0.03(mol.), reaction temperature was 90 ℃, reaction time was 45 min. The yield of acetic ether was up to 94.3%.