无机材料学报
無機材料學報
무궤재료학보
JOURNAL OF INORGANIC MATERIALS
2001年
3期
497-502
,共6页
郑家贵%蔡亚平%周心明%蒋立新%罗四维
鄭傢貴%蔡亞平%週心明%蔣立新%囉四維
정가귀%채아평%주심명%장립신%라사유
Cr203涂层%α-A1203绝缘瓷%二次电子发射特性
Cr203塗層%α-A1203絕緣瓷%二次電子髮射特性
Cr203도층%α-A1203절연자%이차전자발사특성
用CT203涂复α-A1203绝缘瓷表面,并经热退火处理。观测了它们的二次电子发射系数、SEM、XRD、XPS和EELS,发现样品在退火后,涂层元素扩散进了A1203陶瓷基底,生成了新相;根据XPS和EELS的分析结果,表面层能隙减小,能隙中的缺陷态、杂质态及表面态增加,提供了更多可能的复合中心和陷阱中心,有利于非平衡载流子的散射跃迁,从而大大耗散能量,减少二次电子发射。
用CT203塗複α-A1203絕緣瓷錶麵,併經熱退火處理。觀測瞭它們的二次電子髮射繫數、SEM、XRD、XPS和EELS,髮現樣品在退火後,塗層元素擴散進瞭A1203陶瓷基底,生成瞭新相;根據XPS和EELS的分析結果,錶麵層能隙減小,能隙中的缺陷態、雜質態及錶麵態增加,提供瞭更多可能的複閤中心和陷阱中心,有利于非平衡載流子的散射躍遷,從而大大耗散能量,減少二次電子髮射。
용CT203도복α-A1203절연자표면,병경열퇴화처리。관측료타문적이차전자발사계수、SEM、XRD、XPS화EELS,발현양품재퇴화후,도층원소확산진료A1203도자기저,생성료신상;근거XPS화EELS적분석결과,표면층능극감소,능극중적결함태、잡질태급표면태증가,제공료경다가능적복합중심화함정중심,유리우비평형재류자적산사약천,종이대대모산능량,감소이차전자발사。
Cr2O3 coatings were applied to α-A12O3 insulators and followed by heat treatment in special conditions. Secondary electron emission coefficient, SEM, XRD, XPS and EELS of the samples were measured and observed. During heat treatment, new phases can be formed, because the coatings can penetrate the surfaces of the insulators and mix with α-A12O3. The experimental results of XPS and EELS show that due to the energy gaps of the surfaces decreasing, the densities of defect state, impurity state and surface state in the energy gaps increasing, more recombination centers and trapping centers can be formed, and that is favorable for the transition of non-equilibrium carriers and leading the deerease of secondaty electron emission.