苏州大学学报(自然科学版)
囌州大學學報(自然科學版)
소주대학학보(자연과학판)
JOURNAL OF SUZHOU UNIVERSITY NATURAL SCIENCE
2002年
4期
80-84
,共5页
朱琴玉%戴洁%卞国庆%严泽民%杨巍%张加生
硃琴玉%戴潔%卞國慶%嚴澤民%楊巍%張加生
주금옥%대길%변국경%엄택민%양외%장가생
铜(Ⅰ)%配合物%9'-(4,5-二烷基硫-1,3二硫杂环戊烯-二硫-2-叉)二氮杂芴
銅(Ⅰ)%配閤物%9'-(4,5-二烷基硫-1,3二硫雜環戊烯-二硫-2-扠)二氮雜芴
동(Ⅰ)%배합물%9'-(4,5-이완기류-1,3이류잡배무희-이류-2-차)이담잡물
copper (Ⅰ) complex%4',5'-diaza-9'- [ 4,5-bis(alkylthio)- 1,3-dithiol-2-ylidene] fluorenes
首次用Cu(CH3CN)4ClO4与新型配体9'-(4,5-二烷基硫-1,3-二硫杂环戊烯-2-叉)4',5'-二氮杂芴合成了两种Cu(Ⅰ)配合物,并对配合物进行了元素分析和光谱的测定.提出了一维链状的可能结构.
首次用Cu(CH3CN)4ClO4與新型配體9'-(4,5-二烷基硫-1,3-二硫雜環戊烯-2-扠)4',5'-二氮雜芴閤成瞭兩種Cu(Ⅰ)配閤物,併對配閤物進行瞭元素分析和光譜的測定.提齣瞭一維鏈狀的可能結構.
수차용Cu(CH3CN)4ClO4여신형배체9'-(4,5-이완기류-1,3-이류잡배무희-2-차)4',5'-이담잡물합성료량충Cu(Ⅰ)배합물,병대배합물진행료원소분석화광보적측정.제출료일유련상적가능결구.
Two Cu(Ⅰ) complexes were obtained by reacting [Cu(CH3CN)4]ClO4 with new type of hgands,4', 5'-diaza-9'-[4,5-bis( alkylthio)-1,3-dithiol-2-ylidene] fluorenes. These complexes were measured by elemental analyses and spectra. One dimensional structure of these complexes was proposed.
