合成化学
閤成化學
합성화학
CHINESE JOURNAL OF SYNTHETIC CHEMISTRY
2002年
2期
126-130
,共5页
朱德中%张如芬%尹汉东%马春林
硃德中%張如芬%尹漢東%馬春林
주덕중%장여분%윤한동%마춘림
二苄基二氯化锡%N,N-二甲基荒酸%配合物%晶体结构%合成
二芐基二氯化錫%N,N-二甲基荒痠%配閤物%晶體結構%閤成
이변기이록화석%N,N-이갑기황산%배합물%정체결구%합성
dibenzyltin dichloride%N,N-dimethyldithiocarboxylate%crystal structure
用二苄基二氯化锡与N,N-二甲基荒酸钠反应合成了化合物(PhCH2)2Sn[S2CN(CH3)2]2,通过X-射线确定了其晶体结构,晶胞参数为:单斜晶系,空间群P21/n,a=13.926(5), b=9.832(4), c=17.080(7),β=103.541(6)°, V=2273.7(15)3, Z=4.
用二芐基二氯化錫與N,N-二甲基荒痠鈉反應閤成瞭化閤物(PhCH2)2Sn[S2CN(CH3)2]2,通過X-射線確定瞭其晶體結構,晶胞參數為:單斜晶繫,空間群P21/n,a=13.926(5), b=9.832(4), c=17.080(7),β=103.541(6)°, V=2273.7(15)3, Z=4.
용이변기이록화석여N,N-이갑기황산납반응합성료화합물(PhCH2)2Sn[S2CN(CH3)2]2,통과X-사선학정료기정체결구,정포삼수위:단사정계,공간군P21/n,a=13.926(5), b=9.832(4), c=17.080(7),β=103.541(6)°, V=2273.7(15)3, Z=4.
The compound (PhCH2)2Sn[S2CN(CH3)2]2 was prepared by the reaction of dibenzyltin dichloride with sodium N,N-dimethyldithiocarboxylate. Its crystal structure has been determined by X-ray crystallography. It crystallizes in the monoclinic system, space group P21/n with a=13.926(5), b=9.832(4), c=17.080(7),β=103.541(6)°, V=2273.7(15)3, and Z=4.
