天津大学学报(英文版)
天津大學學報(英文版)
천진대학학보(영문판)
TRANSACTIONS OF TIANJIN UNIVERSITY
2003年
4期
296-301
,共6页
袁才登%缪爱花%许涌深%曹同玉
袁纔登%繆愛花%許湧深%曹同玉
원재등%무애화%허용심%조동옥
emulsion polymerization%Monte Carlo method%mathematical model
The method of mathematical model and further computer simulation is an effective way to the theoretical study of emulsion polymerization and the scale-up of the reactors. In this work, Monte Carlo method has been used to simulate the nucleation of emulsion polymerization. The effects of emulsifier concentration on various parameters such as the number of the particles (Np), the average diameter of the latex particles (Dp), monomer conversion (x) and average radical number per particle (n) have been studied. The quantitative equations between and Np are in accord absolutely with the classical theory of Smith-Ewart.
