中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2010年
z1期
75-78
,共4页
郜芸%卢少勇%远野%焦伟%金相灿%黄国忠
郜蕓%盧少勇%遠野%焦偉%金相燦%黃國忠
고예%로소용%원야%초위%금상찬%황국충
聚合氯化铝%钝化剂%扰动强度%沉积物%磷释放
聚閤氯化鋁%鈍化劑%擾動彊度%沉積物%燐釋放
취합록화려%둔화제%우동강도%침적물%린석방
poly alumina chlorine%inactivation agent%perturbance%sediment%phosphorus release
选取滇池福保湾表层沉积物,以聚合氯化铝为钝化剂,研究了扰动强度对钝化剂抑制沉积物中磷释放的影响.结果表明,当扰动强度低于一定范围时,聚合氯化铝对沉积物中的磷有抑制作用,当转速为0,60,120r/min时,对应的水中磷浓度分别为初始值的62.5%,71.7%和83.4%;当转速达到240r/min时,沉积物会向水中释放大量磷,钝化作用完全被破坏,水中磷浓度为初始值的3.3倍.此外,在转速低于120r/min时,磷形态主要是以无机磷(DIP)为主的溶解性磷(DTP),而转速达到240r/min时,水中DTP/TP<30%,DIP/DTP<40%,即磷形态主要为不溶性磷,溶解性磷中以有机磷(DOP)为主.
選取滇池福保灣錶層沉積物,以聚閤氯化鋁為鈍化劑,研究瞭擾動彊度對鈍化劑抑製沉積物中燐釋放的影響.結果錶明,噹擾動彊度低于一定範圍時,聚閤氯化鋁對沉積物中的燐有抑製作用,噹轉速為0,60,120r/min時,對應的水中燐濃度分彆為初始值的62.5%,71.7%和83.4%;噹轉速達到240r/min時,沉積物會嚮水中釋放大量燐,鈍化作用完全被破壞,水中燐濃度為初始值的3.3倍.此外,在轉速低于120r/min時,燐形態主要是以無機燐(DIP)為主的溶解性燐(DTP),而轉速達到240r/min時,水中DTP/TP<30%,DIP/DTP<40%,即燐形態主要為不溶性燐,溶解性燐中以有機燐(DOP)為主.
선취전지복보만표층침적물,이취합록화려위둔화제,연구료우동강도대둔화제억제침적물중린석방적영향.결과표명,당우동강도저우일정범위시,취합록화려대침적물중적린유억제작용,당전속위0,60,120r/min시,대응적수중린농도분별위초시치적62.5%,71.7%화83.4%;당전속체도240r/min시,침적물회향수중석방대량린,둔화작용완전피파배,수중린농도위초시치적3.3배.차외,재전속저우120r/min시,린형태주요시이무궤린(DIP)위주적용해성린(DTP),이전속체도240r/min시,수중DTP/TP<30%,DIP/DTP<40%,즉린형태주요위불용성린,용해성린중이유궤린(DOP)위주.
To make sure if the inactivation agent on the phosphorus (P) release inhibition can last for long time, the sediments from Fubao Gulf of Lake Dianchi were selected, for the experiment to study the effect of perturbance strength on the P release inactivation capability of the inactivation agent (PAC). When the speed of the stirrer was in a certain range, the inhibition of PAC on P release from the sediment was obvious, when the speeds of the stirrer were at 0r/min, 60r/min and 120r/min the amounts of P in the water were about 62.5%, 71.7% and 83.4% of the initial value, respectively.However, when the speed was at 240r/min, the sediment released a great amount of P to the overlying water, which destroyed the inhibition function of PAC on P release from the sediment. The final value was about 3.3 times of the initial amount. Moreover, the P in the overlying water was mainly composed of dissolved P which was mainly made of inorganic composition. While the perturbance strength was high enough, the ratio of DTP/TP (ratio of dissolved total P to total P) was below 30% and the DIP/DTP (ratio of dissolved inorganic total P to DTP) was below 40%, which means that undissolved phosphorus made up of the main part of the TP and most of the DTP was organic phosphorus.