CAJ | 학술논문

基于1,4-苯二硫乙酸(H2L)及中性含氮配体,水热法合成了两个新的d10金属配合物[ZnClL0.5(bpp)](1)和[Cd2L(phen)4(H2O)2]· L·2.78H2O (2)(bpp=1,3-di(4-pyridyl)propane,phen=1,10-phenanthroline),并通过单晶X-射线衍射、元素分析、红外光谱和热重对其结构进行了表征.结构分析表明,在配合物1中,Zn(Ⅱ)呈现四配位的扭曲四面体构型,进一步连接形成一维双链状结构.在配合物2中,C d(Ⅱ)呈现六配位的扭曲八面体构型,并通过可能存在的氢键及π-π堆积作用,形成最终的三维超分子结构.同时,讨论了两种配合物的固体荧光性质.
기우1,4-분이류을산(H2L)급중성함담배체,수열법합성료량개신적d10금속배합물[ZnClL0.5(bpp)](1)화[Cd2L(phen)4(H2O)2]· L·2.78H2O (2)(bpp=1,3-di(4-pyridyl)propane,phen=1,10-phenanthroline),병통과단정X-사선연사、원소분석、홍외광보화열중대기결구진행료표정.결구분석표명,재배합물1중,Zn(Ⅱ)정현사배위적뉴곡사면체구형,진일보련접형성일유쌍련상결구.재배합물2중,C d(Ⅱ)정현륙배위적뉴곡팔면체구형,병통과가능존재적경건급π-π퇴적작용,형성최종적삼유초분자결구.동시,토론료량충배합물적고체형광성질.
Two d10 complexes assembled by 1,4-benzenebis(thioacetic acid) (H2L) and neutral N-based ligands,[ZnClL0.5 (bpp)] (1) and [Cd2L (phen)4 (H2O)2] · L· 2.78H2O (2) (bpp =1,3-di (4-pyridyl)propane,phen =1,10-phenanthroline),have been hydrothermally synthesized and characterized by single crystal X-ray diffraction,elemental analysis,IR spectroscopy,and TG analysis.In complex 1,Zn(Ⅱ) ion is four-coordinated in a distorted tetrahedron coordination environment and is further linked to a one-dimensional (1D) double chain structure.In complex 2,Cd(Ⅱ) ion is six-coordinated in a distorted octahedral coordination environment,and is linked by possible hydrogen bonds and π-π interactions to form a 3D supramolecular structure.The luminescent property in solid state of the two complexes was also studied and discussed.CCDC:734944,1; 819445,2.