Synthesis and Structure of a New Dinuclear Molybdenum(Ⅰ) Compound with Cyclohexanthiolate Ligand, [Mo2(SC6H11)2(CO)6(CH3CN)2]
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    结构化学 결구화학
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
    2004年 12期 1342-1345 ,共4页

    周张锋%庄伯涛%吴克琛%韦永勤%洪涛%张明昕%莽朝永%刘彩萍%林晨升

    주장봉%장백도%오극침%위영근%홍도%장명흔%망조영%류채평%림신승



    molybdenum(Ⅰ)-compound%synthesis%structure%Mo2S2 core


    The reaction of [Et4N]2[Mo2(SC6H11)2(CO)8] and I2 in MeCN affords a new dinu- clear molybdenum(Ⅰ) complex [Mo2(SC6H11)2(CO)6(CH3CN)2] 1 (Mr = 672.46). The crystal and molecular structures have been determined by X-ray single-crystal diffraction. 1 crystallizes in monoclinic, space group P21/c with a = 9.302(1), b = 15.514(2), c = 9.307(1)(°A), β = 92.979(2)o, V = 1341.4(3)(°A)3, Z = 2, Dc = 1.665 g/cm3, μ = 11.28 cm-1, F(000) = 676, R = 0.0461 and wR = 0.1274 for 1702 observed reflections with I > 2σ(I). 1 possesses a rhombic bimetallic core MoS2Mo with the Mo-Mo bond length of 2.9712(4)(°A) and Mo-S of 2.4821(5)(°A).
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