CAJ | 학술논문

采用固相反应法制备了组成为Bi2-xAgxSr2Co2O8-δ(x=0.0,0.4,0.8,略写为BAC-222)的层状钴氧化物陶瓷.利用X-射线光电子能谱考察该类化合物的电子结构,结果表明钴离子以Co3+和Co4+混合价态形式存在,nCo4+/nCo3+的比例随着Ag掺杂的量增加而增加.Ols光电子谱显示在所有样品中均存在点阵氧和吸附氧.热电性能测试结果显示,随着Ag掺杂量的增加,电导率显著增加而Seebeck系数几乎保持不变,Ag的引入极大的影响了BAC-222的电子输运性质,其功率因子在1123K时达到了1.23×10-4W·m-1·K-2,是一种具有很好应用前景的热电材料.
채용고상반응법제비료조성위Bi2-xAgxSr2Co2O8-δ(x=0.0,0.4,0.8,략사위BAC-222)적층상고양화물도자.이용X-사선광전자능보고찰해류화합물적전자결구,결과표명고리자이Co3+화Co4+혼합개태형식존재,nCo4+/nCo3+적비례수착Ag참잡적량증가이증가.Ols광전자보현시재소유양품중균존재점진양화흡부양.열전성능측시결과현시,수착Ag참잡량적증가,전도솔현저증가이Seebeck계수궤호보지불변,Ag적인입겁대적영향료BAC-222적전자수운성질,기공솔인자재1123K시체도료1.23×10-4W·m-1·K-2,시일충구유흔호응용전경적열전재료.
Layered Co-based ceramics with a nominal composition of Bi2-xAgxSr2Co2O8-δ(x=0.0,0.4,0.8, denoted by BAC-222) were prepared using conventional solid state reaction method. X-ray photoemission spectroscopy (XPS) was used to investigate their electronic structures. The cobalt ions are existed in mixed states of Co3+ and Co4+. It is found that the nCo4+/nCo3+ ratio increases with the Ag doping content. The Ols photoemission spectra show that there are lattice oxygen and chemical absorbed oxygen in all the samples. Meanwhile, the conductivity and Seebeck coefficient of Bi2-xAgxSr2Co2O8-δ were studied. The substitution of Bi3+ by Ag+ results in dramatically increase of the electrical conductivity while the Seebeck coefficient is kept almost unchanged. This abnormal phenomenon means that Ag+ ions play an important role in the electrical transport property of BAC-222. The power factor of Bi1.6Ag0.4Sr2Co2O8-δ reaches 1.23×10-4W·m-14·K-2 at 1123K, which suggests that Bi2-xAgxSr2Co2O8-δ are good potential oxides for thermoelectric application.