过程工程学报
過程工程學報
과정공정학보
The Chinese Journal of Process Engineering
2009年
6期
1127-1131
,共5页
周全%徐航%王光润%王金福
週全%徐航%王光潤%王金福
주전%서항%왕광윤%왕금복
蒸发%含酚废水%癸二酸%颜色%零排放
蒸髮%含酚廢水%癸二痠%顏色%零排放
증발%함분폐수%계이산%안색%령배방
evaporation%wastewater containing phenol%sebacic acid%color%zero-emission
利用蒸发法对癸二酸生产过程含酚废水进行资源化处理.结果表明,初始pH<10,苯酚蒸出率维持在34%,pH>13时,苯酚蒸出率接近0.在碱性条件下获得的硫酸钠粉末呈黄色,且在pH为12.8时颜色最深,利用煅烧或N_2环境下蒸发可消除硫酸钠粉末的颜色.硫酸钠对酚的蒸出率影响较小,随苯酚初始浓度增加酚的蒸出率出现先增后减的趋势.
利用蒸髮法對癸二痠生產過程含酚廢水進行資源化處理.結果錶明,初始pH<10,苯酚蒸齣率維持在34%,pH>13時,苯酚蒸齣率接近0.在堿性條件下穫得的硫痠鈉粉末呈黃色,且在pH為12.8時顏色最深,利用煅燒或N_2環境下蒸髮可消除硫痠鈉粉末的顏色.硫痠鈉對酚的蒸齣率影響較小,隨苯酚初始濃度增加酚的蒸齣率齣現先增後減的趨勢.
이용증발법대계이산생산과정함분폐수진행자원화처리.결과표명,초시pH<10,분분증출솔유지재34%,pH>13시,분분증출솔접근0.재감성조건하획득적류산납분말정황색,차재pH위12.8시안색최심,이용단소혹N_2배경하증발가소제류산납분말적안색.류산납대분적증출솔영향교소,수분분초시농도증가분적증출솔출현선증후감적추세.
The wastewater containing phenol and sodium sulfate was treated by evaporation method. The results show that when the initial pH value is under 10, the evaporation rate of phenol reaches 34%, and phenol is not evaporated when the pH value in solution is above 13. The powder of Na_2SO_4 is yellow under alkali condition and the chromaticity is the deepest at pH 12.8. There are some technologies to eliminate the color of Na_2SO_4, e.g calcination in air circumstances or evaporation in N_2 circumstances. Phenol evaporation process is insignificantly affected by solid sodium sulfate.