CAJ | 학술논문

自制了紫外/拉曼两用的电化学薄层池.观测到了TCNQ在外电场作用下转变为TCNQ~-而后又转变为TCNQ~(2-)的紫外-可见吸收光谱变化的电子转移过程,并且当有氧气存在时,TCNQ~(2-)又被氧化而形成DCTC~-的过程.还观测到了TCNQ在外电场作用下转变为TCNQ~-的傅里叶变换拉曼光谶发生频移的电子转移过程.
자제료자외/랍만량용적전화학박층지.관측도료TCNQ재외전장작용하전변위TCNQ~-이후우전변위TCNQ~(2-)적자외-가견흡수광보변화적전자전이과정,병차당유양기존재시,TCNQ~(2-)우피양화이형성DCTC~-적과정.환관측도료TCNQ재외전장작용하전변위TCNQ~-적부리협변환랍만광참발생빈이적전자전이과정.
The coulometry cell is used by UV/Raman was made by ourselves.Electronic absorption spectra have been obtained for the electron transfer process of TCNQ.The E- lectronic absorption spectra changed for TCNQtransformed toTCNQ~-,then transformed toTCNQ~(2-),and when oxygen exists,TCNQ~(2-)was oxidized to DCTC~-in outside electric field.And Fourier Transform Raman shift have been observed for the electron transfer process of the TCNQ changed into TCNQ~-under the effect of outside electric field.