无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2009年
12期
2202-2206
,共5页
代永成%周丽丽%吴界强%张园园%金琼花
代永成%週麗麗%吳界彊%張園園%金瓊花
대영성%주려려%오계강%장완완%금경화
铜(Ⅱ)%邻苯二甲甘氨酸%晶体结构%氢键
銅(Ⅱ)%鄰苯二甲甘氨痠%晶體結構%氫鍵
동(Ⅱ)%린분이갑감안산%정체결구%경건
copper(Ⅱ)%N-Hphthgly%crystal structure%hydrogen bond
A copper(Ⅱ),complex[Cu(N-phthgly)_2(H_2O)_2]·C_2H_5OH(N-Hphthgly=N-phthaloylglycine)has been synthesized and characterized by elemental analysis,infrared spectroscopy and X-ray crystallography.The complex crystallizes in triclinic space group P1 with a=0.47290(7)nm,b=1.08001(13)nm,c=1.15402(15)nm,α=74.3600(10)°,β=79.151O(10)°,γ=87.918(2)°,V=0.557 37(13)nm~3',Z=1.The central copper atom allows the formation coordination environment with two O(5)atoms of two water ligands and two O(1)atoms of two N-phthgly ligands.The complex forms a step-like 3D structure through the three types of O-H…O hydrogen bonds and the Cu…O weak interaction.
