稀有金属
稀有金屬
희유금속
CHINESE JOURNAL OF RARE METALS
2009年
6期
799-804
,共6页
安建军%王华钰%杜春风%严彪%王军%程光
安建軍%王華鈺%杜春風%嚴彪%王軍%程光
안건군%왕화옥%두춘풍%엄표%왕군%정광
快速凝固法%Al-Si-RE合金%导电率%高能球磨
快速凝固法%Al-Si-RE閤金%導電率%高能毬磨
쾌속응고법%Al-Si-RE합금%도전솔%고능구마
rapid solidification%Al-Si-RE alloys%conductivity%high energy ball mill
对快速凝固法制备得到的Al-20Si-0.35RE合金进行不同时间的高能球磨, 然后对球磨后的粉末进行多次热压变形, 采用XRD, ESEM以及TEM等表征变形前后合金粉末的显微组织, 并对变形后合金的导电性能进行了研究. 研究发现快速凝固Al-20Si-0.35RE合金粉末的显微组织主要由细小的Al-Si固溶体(0.3~0.5 μm)、初晶硅、稀土铝硅化合物(0.16~0.3 μm)组成; 随着球磨时间延长, 颗粒粒径显著减小; 经过多次热压变形后合金晶粒显著细化, 晶格畸变减小, 位错钉扎稀土化合物, 形成类似表面渗流效应, 合金导电率提高至70%IACS.
對快速凝固法製備得到的Al-20Si-0.35RE閤金進行不同時間的高能毬磨, 然後對毬磨後的粉末進行多次熱壓變形, 採用XRD, ESEM以及TEM等錶徵變形前後閤金粉末的顯微組織, 併對變形後閤金的導電性能進行瞭研究. 研究髮現快速凝固Al-20Si-0.35RE閤金粉末的顯微組織主要由細小的Al-Si固溶體(0.3~0.5 μm)、初晶硅、稀土鋁硅化閤物(0.16~0.3 μm)組成; 隨著毬磨時間延長, 顆粒粒徑顯著減小; 經過多次熱壓變形後閤金晶粒顯著細化, 晶格畸變減小, 位錯釘扎稀土化閤物, 形成類似錶麵滲流效應, 閤金導電率提高至70%IACS.
대쾌속응고법제비득도적Al-20Si-0.35RE합금진행불동시간적고능구마, 연후대구마후적분말진행다차열압변형, 채용XRD, ESEM이급TEM등표정변형전후합금분말적현미조직, 병대변형후합금적도전성능진행료연구. 연구발현쾌속응고Al-20Si-0.35RE합금분말적현미조직주요유세소적Al-Si고용체(0.3~0.5 μm)、초정규、희토려규화합물(0.16~0.3 μm)조성; 수착구마시간연장, 과립립경현저감소; 경과다차열압변형후합금정립현저세화, 정격기변감소, 위착정찰희토화합물, 형성유사표면삼류효응, 합금도전솔제고지70%IACS.
The Al-20Si-0.35RE alloy which was prepared by rapid solidification was processed by hot pressing after ball-milled for different time. X-ray diffraction spectrum (XRD), environmental scanning electron microscope (ESEM) and transmission electron microscope (TEM) were used to investigate the microstructure of alloy powder before and after hot pressing. Its conductivity was also studied. The microstructure of as-atomized alloy powder was consisted of fine Al-Si solid solution (0.3~0.5 μm), primary silicon phase and rare earth Al-Si compound (0.16~0.3 μm). With the increase of high energy ball milling time, the size of particles was reduced significantly. After several hot pressing processes, the grains were refined obviously and the distortion of lattice decreased significantly. The conductivity of Al-20Si-0.35RE could be improved to 70%IACS for surface seepage effect induced by the dislocation pinning of rare earth compounds.