广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2011年
14期
56-59
,共4页
捕收剂%一水硬铝石%铝硅酸盐矿物%吸附机理
捕收劑%一水硬鋁石%鋁硅痠鹽礦物%吸附機理
포수제%일수경려석%려규산염광물%흡부궤리
collector%diaspore%aluminosilicate minerals%adsorption mechanism
合成了含有单羧基和双羟肟基的新型螫合捕收剂HAD。研究了其对一水硬铝石和铝硅酸盐矿物的浮选行为及浮选机理。结果表明,该捕收剂在中性条件下能有效分离一水硬铝石与铝硅酸盐矿物。作用机理可能是HAD中-COOH和-CONHOH的O原子之间协作与一水硬铝石表面Al点形成螯合物而发生化学吸附,在铝硅酸盐矿物表面主要发生的是物理吸附。
閤成瞭含有單羧基和雙羥肟基的新型螫閤捕收劑HAD。研究瞭其對一水硬鋁石和鋁硅痠鹽礦物的浮選行為及浮選機理。結果錶明,該捕收劑在中性條件下能有效分離一水硬鋁石與鋁硅痠鹽礦物。作用機理可能是HAD中-COOH和-CONHOH的O原子之間協作與一水硬鋁石錶麵Al點形成螯閤物而髮生化學吸附,在鋁硅痠鹽礦物錶麵主要髮生的是物理吸附。
합성료함유단최기화쌍간우기적신형석합포수제HAD。연구료기대일수경려석화려규산염광물적부선행위급부선궤리。결과표명,해포수제재중성조건하능유효분리일수경려석여려규산염광물。작용궤리가능시HAD중-COOH화-CONHOH적O원자지간협작여일수경려석표면Al점형성오합물이발생화학흡부,재려규산염광물표면주요발생적시물리흡부。
Collector HAD was synthesized, containing both mono - carboxyl group groups. The flotation behaviors of diaspore and aluminosilicate minerals were investigated flotation results revealed that a good separation could be realized by using HAD as co searches in interaction mechanism indicated that the interaction of the collector on the and double - hydroxycarbamoyl by using HAD as collector. The llector in neutral medium. The re- diaspore surface was mainly chemi- cal adsorption, the chemical adsorption of HAD on diaspore may take place through - COOH, - CONHOH and Al sites forming chelate rings, and the adsorption on kaolinite and illite was mainly dominated by physical adsorption.