齐齐哈尔大学学报:自然科学版
齊齊哈爾大學學報:自然科學版
제제합이대학학보:자연과학판
Journal of Qiqihar University(Natural Science Edition)
2011年
6期
64-66
,共3页
邵如意%郭祥峰%贾丽华%平原%刘刚
邵如意%郭祥峰%賈麗華%平原%劉剛
소여의%곽상봉%가려화%평원%류강
量子点%荧光%掺杂
量子點%熒光%摻雜
양자점%형광%참잡
quantum dots%fluorescence%doping
采用低温水热技术,以硫脲为稳定剂,在90℃的水相中合成了发蓝色荧光的Mn^2+和Ce^3+共掺杂的CdS体量子点。用透射电子显微镜对该量子点形貌进行了表征,其直径约为10 nm的球形颗粒。研究了该量子点的紫外-可见吸收光谱、荧光发射光谱以及荧光光谱随时间的变化。结果表明,Mn^2+和Ce^3+共掺杂使CdS量子点的发光强度提高10倍;该量子点具有较好的发光稳定性。
採用低溫水熱技術,以硫脲為穩定劑,在90℃的水相中閤成瞭髮藍色熒光的Mn^2+和Ce^3+共摻雜的CdS體量子點。用透射電子顯微鏡對該量子點形貌進行瞭錶徵,其直徑約為10 nm的毬形顆粒。研究瞭該量子點的紫外-可見吸收光譜、熒光髮射光譜以及熒光光譜隨時間的變化。結果錶明,Mn^2+和Ce^3+共摻雜使CdS量子點的髮光彊度提高10倍;該量子點具有較好的髮光穩定性。
채용저온수열기술,이류뇨위은정제,재90℃적수상중합성료발람색형광적Mn^2+화Ce^3+공참잡적CdS체양자점。용투사전자현미경대해양자점형모진행료표정,기직경약위10 nm적구형과립。연구료해양자점적자외-가견흡수광보、형광발사광보이급형광광보수시간적변화。결과표명,Mn^2+화Ce^3+공참잡사CdS양자점적발광강도제고10배;해양자점구유교호적발광은정성。
Ce^3+ and Cd^2+ co-doped CdS quantum dots(QDs) were synthesized in an aqueous solution at 90℃ using thiourea as a stabilizer.The as-prepared samples were characterized by transmission electron microscope.The prepared product was proved to be sphericity QDs and the diameter of about 10 nm.The as-prepared undoped and the Ce3+ and Mn2+ co-doped CdS QDs were characterized by UV-Vis spectrum and fluorescence spectrum.Results show that the co-doped CdS QDs have a better fluoresence intensity and stability than undoped CdS QDs.