化工新型材料
化工新型材料
화공신형재료
NEW CHEMICAL MATERIALS
2010年
4期
58-60
,共3页
白青龙%张春花%程传辉%夏道成%范昭奇%杜国同
白青龍%張春花%程傳輝%夏道成%範昭奇%杜國同
백청룡%장춘화%정전휘%하도성%범소기%두국동
苯氧基金属酞菁%合成%表征%光谱性质
苯氧基金屬酞菁%閤成%錶徵%光譜性質
분양기금속태정%합성%표정%광보성질
phenoxy-metal phthalocyanine%synthesis%characterization%spectrum property
以3-硝基邻苯二腈和4-硝基邻苯二腈为原料分别合成了1,8,15,22-四-苯氧基酞菁铜(镍)和2,9,16,23-四-苯氧基酞菁铜(镍),通过IR和UV-Vis光谱进行了表征,并讨论了取代基的取代位置和中心离子对酞菁Q带最大吸收波长的影响.
以3-硝基鄰苯二腈和4-硝基鄰苯二腈為原料分彆閤成瞭1,8,15,22-四-苯氧基酞菁銅(鎳)和2,9,16,23-四-苯氧基酞菁銅(鎳),通過IR和UV-Vis光譜進行瞭錶徵,併討論瞭取代基的取代位置和中心離子對酞菁Q帶最大吸收波長的影響.
이3-초기린분이정화4-초기린분이정위원료분별합성료1,8,15,22-사-분양기태정동(얼)화2,9,16,23-사-분양기태정동(얼),통과IR화UV-Vis광보진행료표정,병토론료취대기적취대위치화중심리자대태정Q대최대흡수파장적영향.
We synthesized 1,8,15,22-tetra-phenoxy-copper(nickel) phthalocyanine,1,8,15,22-tetra-phenoxy-nickel phthalocyanine,2,9,16,23-tetra-phenoxy-eopper phthalocyanine and 2,9,16,23-tetra-phenoxy-nickel phthalocya-nine.The major precursors were 3-nitrobenzene-1,2-dicarbonitrile and 4-nitrobenzene-1,2-dicarbonitrile,respectively.They were characterized by elemental analysis,IR and UV-Vis,respectively.We also discussed the influence of the substi-tution position and the central metal ion on the maximum absorption wavelength of the phthalocyanine Q-band.
