CAJ | 학술논문

利用Penning ion trap获得了七种不同延时时间(即反应时间)的离子谱Hn+(n≤4)，用充分的实验数据证实了H4+是稳定的，稳定时间达1秒量级。实验结果显示：H4+是经合成反应H2++H2→H4+，H3++H+H2→H4++H2产生的；H4+的分解产物是H3++H。分析得出：H4+构型为H3+-核构型。
이용Penning ion trap획득료칠충불동연시시간(즉반응시간)적리자보Hn+(n≤4)，용충분적실험수거증실료H4+시은정적，은정시간체1초량급。실험결과현시：H4+시경합성반응H2++H2→H4+，H3++H+H2→H4++H2산생적；H4+적분해산물시H3++H。분석득출：H4+구형위H3+-핵구형。
We obtain seven spectra of Hn+(n≤4) cluster ions at different delay time using a penning ion trap. The data is adequate to confirm that H4+ is stable cluster ions for 1s. The experimental results suggest that H4+　is formed by reaction H3+ + H + H2 → H4+ + H2, H2+ + H2 → H4+; the dissociation production of H4+ is H3+; and H4+ configuration is a H3+-core weakly bonded by a ligand H atom