药学学报
藥學學報
약학학보
ACTA PHARMACEUTICA SINICA
2007年
9期
959-963
,共5页
李春%岳党昆%卜鹏滨%孙有富
李春%嶽黨昆%蔔鵬濱%孫有富
리춘%악당곤%복붕빈%손유부
血党%1,4-苯醌%烷基酚%belamcandaquinone F%ardisiphenol D
血黨%1,4-苯醌%烷基酚%belamcandaquinone F%ardisiphenol D
혈당%1,4-분곤%완기분%belamcandaquinone F%ardisiphenol D
Ardisia punctata%1,4-benzoquinone%alkylphenol%belamcandaquinone F%ardisiphenol D
为了系统研究广西草药血党的化学成分.本文采用多种色谱技术和光谱技术对血党根部进行了分离提取和结构鉴定.从石油醚提取部位分离得到两个新化合物,经鉴定其结构分别为2-十三烷基-3-[(2-十三烷基-4-乙酰氧基-6-甲氧基)-苯氧基]-6-甲氧基-1,4-苯醌(1)和2-甲氧基-4-羟基-6-十三烷基-乙酸苯酯(2).化合物1,2均为新化合物.
為瞭繫統研究廣西草藥血黨的化學成分.本文採用多種色譜技術和光譜技術對血黨根部進行瞭分離提取和結構鑒定.從石油醚提取部位分離得到兩箇新化閤物,經鑒定其結構分彆為2-十三烷基-3-[(2-十三烷基-4-乙酰氧基-6-甲氧基)-苯氧基]-6-甲氧基-1,4-苯醌(1)和2-甲氧基-4-羥基-6-十三烷基-乙痠苯酯(2).化閤物1,2均為新化閤物.
위료계통연구엄서초약혈당적화학성분.본문채용다충색보기술화광보기술대혈당근부진행료분리제취화결구감정.종석유미제취부위분리득도량개신화합물,경감정기결구분별위2-십삼완기-3-[(2-십삼완기-4-을선양기-6-갑양기)-분양기]-6-갑양기-1,4-분곤(1)화2-갑양기-4-간기-6-십삼완기-을산분지(2).화합물1,2균위신화합물.
To study the chemical constituents of Ardisia punctata,compounds were isolated with a combination of multi-chromatography.Their structures were determined on the basis of spectral analysis and comparison to those of the known compounds.A 1,4-benzoquinone derivative and a alkylphenol were isolated from the petroleum ether extract of the roots of Ardisia punctata.Their structures were elucidated as 2-tridecyl-3-[(2-tridecyl-4-acetoxy-6-methoxy)-phenoxyl]-6-methoxy-1,4-benzoquinone (1) and 2-methoxy-4-hydroxy-6-tridecyl-phenyl acetate (2).The two compounds are both new.