CAJ | 학술논문

由于Diels-Alder反应具有一系列重要特点(原子经济性、热可逆性、立体选择性、立体专一性和区域选择性等),自从1928年被发现以来,该反应就一直是人们研究的热点.将其应用于聚合物的合成中,可制备一些具有特殊性能的Diels-Alder聚合物,人们在这方面作了大量的研究工作,取得了许多研究成果.本文首先根据不同的分类标准,对应用Diels-Alder反应制备聚合物的研究进行了分类,然后结合本课题组的相关研究工作,综述了近年来人们在该领域的研究进展,最后展望了其研究前景.
유우Diels-Alder반응구유일계렬중요특점(원자경제성、열가역성、입체선택성、입체전일성화구역선택성등),자종1928년피발현이래,해반응취일직시인문연구적열점.장기응용우취합물적합성중,가제비일사구유특수성능적Diels-Alder취합물,인문재저방면작료대량적연구공작,취득료허다연구성과.본문수선근거불동적분류표준,대응용Diels-Alder반응제비취합물적연구진행료분류,연후결합본과제조적상관연구공작,종술료근년래인문재해영역적연구진전,최후전망료기연구전경.
Diels-Alder reaction has been a hot topic in academe ever since its discovery in 1928 due to its important properties, such as atom economy, thermo-reversibility, regioselectivity, stereospecificity and stereoselectivity. Diels-Alder polymer is obtained by utilizing Diels-Alder reaction in polymer preparation, in which a lot of work has been done. In this paper, research progress in this field is classified from different stand point, and then is summarized, including our relative work in the field. Finally, the development prospects of polymer based on Diels-Alder reaction are also presented.