日用化学工业
日用化學工業
일용화학공업
CHINA SURFACTANT DETERGENT & CONSMETICS
2001年
1期
49-50,56
,共3页
滴体积法%表面张力%校正系数%曲线拟合
滴體積法%錶麵張力%校正繫數%麯線擬閤
적체적법%표면장력%교정계수%곡선의합
应用无约束优化的Powell方法和多元回归方法,对滴体积法测定表面张力计算公式中的校正系数进行曲线拟合。按照V/R3数值,给出了校正系数的分段近似解析表达式,拟合值与实测值相对偏差小于0.3%。应用校正系数拟合函数,可以将测定的液滴体积代入公式直接计算表面张力。该种计算方法省去了查表确定校正系数的步骤便于在计算机上应用。
應用無約束優化的Powell方法和多元迴歸方法,對滴體積法測定錶麵張力計算公式中的校正繫數進行麯線擬閤。按照V/R3數值,給齣瞭校正繫數的分段近似解析錶達式,擬閤值與實測值相對偏差小于0.3%。應用校正繫數擬閤函數,可以將測定的液滴體積代入公式直接計算錶麵張力。該種計算方法省去瞭查錶確定校正繫數的步驟便于在計算機上應用。
응용무약속우화적Powell방법화다원회귀방법,대적체적법측정표면장력계산공식중적교정계수진행곡선의합。안조V/R3수치,급출료교정계수적분단근사해석표체식,의합치여실측치상대편차소우0.3%。응용교정계수의합함수,가이장측정적액적체적대입공식직접계산표면장력。해충계산방법성거료사표학정교정계수적보취편우재계산궤상응용。
The curve fitting of correct coefficient in the dropvolume method for determination of surface tension was carried out by means of Powell method and multivariate regression. According to the value of V/R3, the approximate analytical expressions were given respectively. The relative deviation between fitting value and experimental value is less than 0.3 %. By application of the fitting function of correct coefficient, the surface tension may be obtained by direct calculation with the volume of drop Ⅴ. Because of obviation of looking up a correct coefficient in the table, the calculation is easy to operate by computer.