安徽大学学报(自然科学版)
安徽大學學報(自然科學版)
안휘대학학보(자연과학판)
JOURNAL OF ANHUI UNIVERSITY(NATURAL SCIENCES EDITION)
2012年
5期
37-42
,共6页
张星%李广%何灏%贺文兰%丁伯江
張星%李廣%何灝%賀文蘭%丁伯江
장성%리엄%하호%하문란%정백강
YAG:Ce3+荧光粉%5d-4f电子跃迁%Ce3+掺杂浓度%烧结温度
YAG:Ce3+熒光粉%5d-4f電子躍遷%Ce3+摻雜濃度%燒結溫度
YAG:Ce3+형광분%5d-4f전자약천%Ce3+참잡농도%소결온도
YAG:Ce3+ phosphor%5d-4f transition%concentration of doped Ce3+%sintering temperature
由于YAG:Ce3+荧光粉在白光发光二极管中的广泛应用,使其受到越来越多的关注.但是出于商业利益,其最佳配方和烧结工艺却是保密的.利用固相法,通过控制所掺杂Ce3+的浓度及调节烧结温度制备一系列YAG:Ce3+荧光粉.测试结果表明:当激发光波长为460 nm时,该荧光粉的发射波长为540 nm;最佳掺杂Ce3+的浓度及烧结温度分别为2%和1 400℃;此外,发射波长有红移的现象,此更符合现代固态照明对色度的需要.
由于YAG:Ce3+熒光粉在白光髮光二極管中的廣汎應用,使其受到越來越多的關註.但是齣于商業利益,其最佳配方和燒結工藝卻是保密的.利用固相法,通過控製所摻雜Ce3+的濃度及調節燒結溫度製備一繫列YAG:Ce3+熒光粉.測試結果錶明:噹激髮光波長為460 nm時,該熒光粉的髮射波長為540 nm;最佳摻雜Ce3+的濃度及燒結溫度分彆為2%和1 400℃;此外,髮射波長有紅移的現象,此更符閤現代固態照明對色度的需要.
유우YAG:Ce3+형광분재백광발광이겁관중적엄범응용,사기수도월래월다적관주.단시출우상업이익,기최가배방화소결공예각시보밀적.이용고상법,통과공제소참잡Ce3+적농도급조절소결온도제비일계렬YAG:Ce3+형광분.측시결과표명:당격발광파장위460 nm시,해형광분적발사파장위540 nm;최가참잡Ce3+적농도급소결온도분별위2%화1 400℃;차외,발사파장유홍이적현상,차경부합현대고태조명대색도적수요.
YAG:Ce3+ phosphor receives extensive interest owing to its applications in the light emitting diode (LED) for white LED lighting.But the optimum prescription and the sintering technology of the phosphor are secret because of commercial profit.For this reason,a series of YAG:Ce3+ phosphors of high performance with diverse photoluminescence properties were prepared and obtained via controlling the Ce3+ doped concentration and adjusting the sintering temperature by solid state reaction.The results indicated that when they were excited by the blue source with wavelength of 460 nm,bright yellow emission locating at 540 nm would be observed. Furthermore, the optimal concentration of Ce3+ and the optimal sintering temperature were found to be 2% and 1 400 ℃,respectively. In addition,the emission wavelength shifted to the red direction,which would meet the solid- state white lighting requirements of chromaticity.