含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2009年
6期
694-698
,共5页
盛涤伦%马凤娥%张裕峰%朱雅红%陈利魁%杨斌
盛滌倫%馬鳳娥%張裕峰%硃雅紅%陳利魁%楊斌
성조륜%마봉아%장유봉%주아홍%진리괴%양빈
物理化学%钴(Ⅲ)配合物%晶体结构%激光化学感度
物理化學%鈷(Ⅲ)配閤物%晶體結構%激光化學感度
물이화학%고(Ⅲ)배합물%정체결구%격광화학감도
physical chemistry%cobalt(Ⅲ)complex%crystal structure%laser sensitivity
制备了高氯酸·四氨·双叠氮基合钴(Ⅲ)(DACP)的单晶,用X-ray单晶面探衍射仪测定了其晶体结构.结果表明,晶体属三斜晶系,空间群为P-1.晶体学参数为:a=0.74229(9)nm,α=93.244(2)°b=1.21273(14)nm,β=100.074(2)°;c=1.8124(2)nm,γ=98.033(2)°.晶胞体积V=1.5851(3)nm~3,晶胞分子数Z=6,计算密度D_c=1.952 mg·mm~(-3),线性吸收系数μ=1.901 mm~(-1),单胞中电子数目F(000)=948.该化合物对635 nm的激光非常敏感.
製備瞭高氯痠·四氨·雙疊氮基閤鈷(Ⅲ)(DACP)的單晶,用X-ray單晶麵探衍射儀測定瞭其晶體結構.結果錶明,晶體屬三斜晶繫,空間群為P-1.晶體學參數為:a=0.74229(9)nm,α=93.244(2)°b=1.21273(14)nm,β=100.074(2)°;c=1.8124(2)nm,γ=98.033(2)°.晶胞體積V=1.5851(3)nm~3,晶胞分子數Z=6,計算密度D_c=1.952 mg·mm~(-3),線性吸收繫數μ=1.901 mm~(-1),單胞中電子數目F(000)=948.該化閤物對635 nm的激光非常敏感.
제비료고록산·사안·쌍첩담기합고(Ⅲ)(DACP)적단정,용X-ray단정면탐연사의측정료기정체결구.결과표명,정체속삼사정계,공간군위P-1.정체학삼수위:a=0.74229(9)nm,α=93.244(2)°b=1.21273(14)nm,β=100.074(2)°;c=1.8124(2)nm,γ=98.033(2)°.정포체적V=1.5851(3)nm~3,정포분자수Z=6,계산밀도D_c=1.952 mg·mm~(-3),선성흡수계수μ=1.901 mm~(-1),단포중전자수목F(000)=948.해화합물대635 nm적격광비상민감.
The single crystal of tetraamminediazido cobalt(Ⅲ)perchlorate(DACP)was prepared,and its crystal structure was determined by a X-ray single crystal diffractometer.The results show that the crystal is triclinic belonging to space group of P-1 with crystal parameters of the unit cell dimensions: a=0.74229(9)nm,α =93.244(2)°,b = 1.21273(14)nm,β = 100.074(2)°,c = l.8124(2)nm,γ=98.033(2)°,volume V= 1.5851(3)nm~3,Z = 6,calculated density D_c = 1.952 mg· mm~(-3),absorption coefficient μ = 1.901 mm~(-1),F(000)=948.The compound is very sensitive to laser with a wavelength of 635 nm.