CAJ | 학술논문

总结了作者近几年在硼磷酸盐研究中所合成和表征的10多个新化合物，即元素周期表第4周期从Cr至Ga的元素或氧化物与工业催化剂材料BPO．在高温固相反应中，分别合成出具有3种结构类型的新化合物：新结构类型的三方Cr2[BP3O12]、正交AlPO4型的(B，M)[PO4](M=Mn，Fe．Co，Ni，Cu，Zn)和新型四方(Ga，B)PO4；用水热法合成出NaGa[BP2O7(OH)3]、Na2In2[PO3(OH)]4·H2O和Na4Co3H2(PO4)4·8H2O等新化合物．同时还讨论了硼磷酸盐化合物研究的最新进展及结构化学的一般规律．
총결료작자근궤년재붕린산염연구중소합성화표정적10다개신화합물，즉원소주기표제4주기종Cr지Ga적원소혹양화물여공업최화제재료BPO．재고온고상반응중，분별합성출구유3충결구류형적신화합물：신결구류형적삼방Cr2[BP3O12]、정교AlPO4형적(B，M)[PO4](M=Mn，Fe．Co，Ni，Cu，Zn)화신형사방(Ga，B)PO4；용수열법합성출NaGa[BP2O7(OH)3]、Na2In2[PO3(OH)]4·H2O화Na4Co3H2(PO4)4·8H2O등신화합물．동시환토론료붕린산염화합물연구적최신진전급결구화학적일반규률．
Borophosphates have attracted much attention of scientists in the last few years due to the potential applications of these compounds as functional materials. More than ten new compounds in the related systems have been synthesized and characterized here by either solid state reactions or hydrothermal methods. The new compounds have either new structure types like Cr2BP3O12 which contains new building motif, or with very well known structure type like low cristobalite. The general structural features of these compounds have been discussed together with the literature data, and the new developments of the borophosphate research have also been reviewed here.