化工环保
化工環保
화공배보
ENVIRONMENTAL PROTECTION OF CHEMICAL INDUSTRY
2001年
2期
84-87
,共4页
太阳光%光氧化降解%草酸铁络合物%过氧化氢%染料%直接耐酸大红
太暘光%光氧化降解%草痠鐵絡閤物%過氧化氫%染料%直接耐痠大紅
태양광%광양화강해%초산철락합물%과양화경%염료%직접내산대홍
以H2O2/草酸铁络合物作光氧化剂,利用太阳光对水溶液中的直接耐酸大红进行了光氧化降解试验研究。结果表明,在日光照射下,H2O2/草酸铁络合物能使溶液中直接耐酸大红迅速光解,晴天光照15 min或阴天光照30~40 min,溶液(直接耐酸大红的质量浓度为50 mg/L)可褪至无色;溶液的初始pH对染料光解有显著影响,pH为2~4时光解效果最佳;提高H2O2浓度可以提高光解速率,但H2O2的利用率会降低。
以H2O2/草痠鐵絡閤物作光氧化劑,利用太暘光對水溶液中的直接耐痠大紅進行瞭光氧化降解試驗研究。結果錶明,在日光照射下,H2O2/草痠鐵絡閤物能使溶液中直接耐痠大紅迅速光解,晴天光照15 min或陰天光照30~40 min,溶液(直接耐痠大紅的質量濃度為50 mg/L)可褪至無色;溶液的初始pH對染料光解有顯著影響,pH為2~4時光解效果最佳;提高H2O2濃度可以提高光解速率,但H2O2的利用率會降低。
이H2O2/초산철락합물작광양화제,이용태양광대수용액중적직접내산대홍진행료광양화강해시험연구。결과표명,재일광조사하,H2O2/초산철락합물능사용액중직접내산대홍신속광해,청천광조15 min혹음천광조30~40 min,용액(직접내산대홍적질량농도위50 mg/L)가퇴지무색;용액적초시pH대염료광해유현저영향,pH위2~4시광해효과최가;제고H2O2농도가이제고광해속솔,단H2O2적이용솔회강저。
The photooxidative degradation of Direct Fast Scarlet dyes in aqueous solution under solar irradiation by H2O2/ferrioxalate complexes has been studied.The results indicate that the dyes in the solution can be rapidly degraded by the process.The dye solution (50 mg/L of mass concentration)is completely decolored after15 min of irradiation under sunny sky or 30~40 min under overcast sky.The initial pH of thesolution has significant effect on the photolysis.The efficiency of photolysis is highest at pH 2~4.The destruction rate of the dyes is increased with increasing concentration of H2O2,but the utilization efficiency of H2O2 is decreased at high level of H2O2.