CAJ | 학술논문

综述了以ABn(n=2,3,4)型单体制备超支化聚碳硅烷、超支化聚碳硅氧烷和超支化聚烷氧基硅烷三类超支化有机硅树脂的合成工艺及其改性技术,重点介绍了制备含不饱和双键和环氧基团的功能性超支化有机硅树脂单体的分子设计与制备技术.论述了超支化有机硅树脂在薄膜材料、复合催化刺、增强助剂等领域的应用研究进展.
종술료이ABn(n=2,3,4)형단체제비초지화취탄규완、초지화취탄규양완화초지화취완양기규완삼류초지화유궤규수지적합성공예급기개성기술,중점개소료제비함불포화쌍건화배양기단적공능성초지화유궤규수지단체적분자설계여제비기술.논술료초지화유궤규수지재박막재료、복합최화자、증강조제등영역적응용연구진전.
Synthesis and modification technology of hyperbranehed organosilicon resins from ABn(n= 2,3,4) mon-omers were summarized in detail, including hyperbranehed polycarbosilanes, hyperbranched polycarbosiloxanes and hyper-branched polyalkoxysilanes. Especially, monomer molecular designation and preparation method of funcational hyper-branched organosilicon resins containing unsaturated double-bonds and epoxy group also were diseuused. Application pro-gress of hyperbranched organosilicon resins in membrane materials, complex catalysts and reinforcement additives fields were reviewed.