浙江大学学报（英文版）
浙江大學學報（英文版）
절강대학학보（영문판）
JOURNAL OF ZHEJIANG UNIVERSITY SCIENCE
2004年
10期
1175-1179
,共5页
张永敏%林茂钦%俞永平
張永敏%林茂欽%俞永平
장영민%림무흠%유영평
Grignard reagent%Cp2TiCl2-catalyzed%α-diketone%β-diketone%Reduction
α-diketones and β-diketones react with Grignard reagents in the presence of a catalytic amount of Cp2TiCl2 to yield α-ketols and corresponding ketones respectively. Sulfoxides can be deoxygenated by Cp2TiCl2/Al system. The possible mechanisms are also discussed.
