CAJ | 학술논문

收集了15种铁-镁电气石的晶体结构数据,计算了固有电偶极矩,分析了铁-镁电气石的固有电偶极矩与铁含量、价态及分布的关系.结果显示:电气石中沿着c轴方向的固有电偶极矩随着Fe3+离子总数、特别是Y位置上Fe3+离子数的增加而减小,随Y位置上Fe2+离子数的增加而略有增加.
수집료15충철-미전기석적정체결구수거,계산료고유전우겁구,분석료철-미전기석적고유전우겁구여철함량、개태급분포적관계.결과현시:전기석중연착c축방향적고유전우겁구수착Fe3+리자총수、특별시Y위치상Fe3+리자수적증가이감소,수Y위치상Fe2+리자수적증가이략유증가.
Crystal structure data of 15 iron-magnesium (Fe-Mg) tourmalines have been collected and their intrinsic dipole moments have been calculated. The correlation between the content, valence and distribution of Fe in Fe-Mg tourmalines and their intrinsic dipole moments have been analyzed in detail. The results show that the intrinsic dipole moments along the c axis in Fe-Mg tourmalines decrease with the increasing of their Fe3+ content, especially the content of Fe3+ in Y polyhedra, and slightly increase with the increasing of the content of Fe2+ in Y polyhedra.