CAJ | 학술논문

过渡金属膦配合物在有机合成和催化反应中的应用非常广泛,大量含膦杂原子配体被设计合成,利用其特定的配位能力,和过渡金属配位成过渡金属膦配合物,并测试其对特定有机化学反应的催化性能.硅氢加成反应是有机硅化学中的重要反应,多种过渡金属包括铂、钯、铑、钌等的膦配合物对于硅氢加成反应均有催化活性.综述了近几年来过渡金属膦配合物在硅氢加成反应中的应用进展.
과도금속련배합물재유궤합성화최화반응중적응용비상엄범,대량함련잡원자배체피설계합성,이용기특정적배위능력,화과도금속배위성과도금속련배합물,병측시기대특정유궤화학반응적최화성능.규경가성반응시유궤규화학중적중요반응,다충과도금속포괄박、파、로、조등적련배합물대우규경가성반응균유최화활성.종술료근궤년래과도금속련배합물재규경가성반응중적응용진전.
Transition metal-phosphorus complexes are very important for the organic synthesis and catalytic reactions. Many phosphorus ligands and heteroatom ligands containing phosphorus were synthesized. On the other hand, hydrosilylation is one of the most important reactions in organosilicon chemistry, and many organosilicon monomers containing functional groups have been synthesized via this reaction. The catalytic hydrosilylation process is well established, and many transition metals such as platinum, palladium, rhodium, ruthenium or other transition metal phosphorus complexes are widely used in hydrosilylation reactions, though it is still desirable to further increase the catalytic activity and selectivity and to minimize the amount of catalyst. In this paper, the progress of transition metal-phosphorus complexes in hydrosilylation during recent years is reviewed.