稀有金属材料与工程
稀有金屬材料與工程
희유금속재료여공정
RARE METAL MATERIALS AND ENGINEERNG
2004年
5期
494-497
,共4页
白新德%彭德全%贺非%尤引娟%王瑞偏%陆金发%苏亲善
白新德%彭德全%賀非%尤引娟%王瑞偏%陸金髮%囌親善
백신덕%팽덕전%하비%우인연%왕서편%륙금발%소친선
点蚀%A0纯铝%模拟%阳极极化%电极电位%酸化
點蝕%A0純鋁%模擬%暘極極化%電極電位%痠化
점식%A0순려%모의%양겁겁화%전겁전위%산화
pit corrosion%A0 pure aluminum%simulating%anode polarization%potential%acidification
测量A0纯铝在去离子水中的极化曲线用来模拟反应堆池壳的点蚀.研究表明:A0纯铝在去离子水中很容易钝化.实验中用美国EG&G普林斯顿应用研究公司生产的273型恒电位/恒电流仪测量模拟孔电位,极化曲线表明:模拟腐蚀坑处于钝化状态,即便是氧化膜破裂,腐蚀坑也发展得很慢.用pH计测量孔中pH的变化,并得到其工作曲线,此曲线表明:带有氧化膜的点蚀坑坑内存在明显的酸化现象.并对A0铝池壳的服务寿命进行了估计.
測量A0純鋁在去離子水中的極化麯線用來模擬反應堆池殼的點蝕.研究錶明:A0純鋁在去離子水中很容易鈍化.實驗中用美國EG&G普林斯頓應用研究公司生產的273型恆電位/恆電流儀測量模擬孔電位,極化麯線錶明:模擬腐蝕坑處于鈍化狀態,即便是氧化膜破裂,腐蝕坑也髮展得很慢.用pH計測量孔中pH的變化,併得到其工作麯線,此麯線錶明:帶有氧化膜的點蝕坑坑內存在明顯的痠化現象.併對A0鋁池殼的服務壽命進行瞭估計.
측량A0순려재거리자수중적겁화곡선용래모의반응퇴지각적점식.연구표명:A0순려재거리자수중흔용역둔화.실험중용미국EG&G보림사돈응용연구공사생산적273형항전위/항전류의측량모의공전위,겁화곡선표명:모의부식갱처우둔화상태,즉편시양화막파렬,부식갱야발전득흔만.용pH계측량공중pH적변화,병득도기공작곡선,차곡선표명:대유양화막적점식갱갱내존재명현적산화현상.병대A0려지각적복무수명진행료고계.
The anode polarization curve of A0 pure aluminum in DI (de-ions) water was measured to simulate the pit corrosion of reactor pool shell. It confirmed the A0 aluminum is easy to passivate in DI water. The potential in the pit were determined with EG&G Princeton Applied Research Potentiostat/ Galvanostat Model 273, the polarization curve shows that the simulated corrosion pit was in passivated situation, even ifthe oxidization film was broken, the corrosion pit will probably develop slowly, the varied pH in pit was determined with pH measurer, and the working curves were obtained, which shows the obvious acidification exists in pit for the sample with oxidization film. The service life of A0 aluminum pool shell was estimated.
Key words: pit corrosion; A0 pure aluminum; simulating; anode polarization; potential; acidification