无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2010年
7期
1311-1314
,共4页
陈静%尹建玲%王晓娟%冯云龙
陳靜%尹建玲%王曉娟%馮雲龍
진정%윤건령%왕효연%풍운룡
1,4-苯二硫乙酸%晶体结构%双螺旋结构%荧光
1,4-苯二硫乙痠%晶體結構%雙螺鏇結構%熒光
1,4-분이류을산%정체결구%쌍라선결구%형광
1,4-benzenebis(thioacetic acid)%crystal structure%double helix structure%luminescent property
A flexible carboxylic ligand, l,4-benzenebis(thioacetic acid) (H2L), has been employed to assemble with Cd(Ⅱ) ions under hydrothermal conditions, generating a new complex [Cd2L2(2,2'-bipy)2]n (1). X-ray diffraction reveals the complex 1 possesses a self-assembly double helix structure deriving from [Cd2L2(2,2'-bipy)2] units linked by L2-ligands. A 3D infinite framework is constructed via π-π stacking of 2,2'-bipy. The photoluminescent properties in solid state were investigated.
