CAJ | 학술논문

通过将相应的席夫碱穴醚还原的方法合成了三个具有不同取代基(R=溴,4;苯基,5;甲基,6)的新的酚羟基桥的八胺穴醚,并对其进行了表征.将这些新穴醚与镧系元素的高氯酸盐反应制备了它们的镧系元素配合物(7～12).核磁、质谱、红外、紫外和元素分析等表征结果表明这些镧系元素配合物为单核配合物并可能具有N3O3N3型的对称配位结构.讨论了铕(Ⅲ)配合物8在乙腈溶液中的荧光性质.
통과장상응적석부감혈미환원적방법합성료삼개구유불동취대기(R=추,4;분기,5;갑기,6)적신적분간기교적팔알혈미,병대기진행료표정.장저사신혈미여란계원소적고록산염반응제비료타문적란계원소배합물(7～12).핵자、질보、홍외、자외화원소분석등표정결과표명저사란계원소배합물위단핵배합물병가능구유N3O3N3형적대칭배위결구.토론료유(Ⅲ)배합물8재을정용액중적형광성질.
Three new Phenolate-bridged octaamino cryptands(R=Bromo,4;Phenyl,5;Methyl,6) were synthesized in high yield by reduction of the corresponding robson-tybe cryptands derived from a 2+3 Condensation of tris(2-aminoethyl)-amine and 2,6-diformy1-4-R-Phenol.The lanthanide cryptates (7～12) were obtained by treating the cryptands with lanthanide perchlorates.All compounds were carefully characterized by NMR,mass spectra,IR,UV-Vis and elemental analyses.A new type of N3O3N3 symmetric coordination geometry around themononuclear lanthanide(Ⅲ) ion encapsulated within the cryptand cavity was proposed.The Luminescence property of europium(Ⅲ) crypate 8 in acetonitrile solution was also discussed.