CAJ | 학술논문

旨在研究一系列5,6-去甲斑蝥酰亚胺衍生物的质谱裂解特征.研究结果显示异口恶唑并N-取代去甲去氢斑蝥酰亚胺衍生物,即各种1,3-偶极子氧化腈"现场"与N-取代斑蝥酰亚胺进行[3+2]环加成的系列产物在电子轰击下,质谱裂解的各种碎片呈现了此系列杂环分子结构环消除的规律性-逆1,3-偶极环加成反应的历程.
지재연구일계렬5,6-거갑반모선아알연생물적질보렬해특정.연구결과현시이구악서병N-취대거갑거경반모선아알연생물,즉각충1,3-우겁자양화정"현장"여N-취대반모선아알진행[3+2]배가성적계렬산물재전자굉격하,질보렬해적각충쇄편정현료차계렬잡배분자결구배소제적규률성-역1,3-우겁배가성반응적역정.
The mass spectra of a series of novel 5,6-dehydronorcantharidin derivatives substituted by aromatic amine have been examined.The paper is to report the preliminary results of an investigation of the mass spectrometric behavior of heterocyclic compounds formed by 1,3-dipolar cycloaddition reaction of nitrile oxides and N-substituted cantharidinimides which is formed by Diels-Alder reaction to show that such compounds upon electron impact may fragment by way of a cyclo-elimination reaction corresponding,formally,to the reverse process of their formation.