CAJ | 학술논문

以山梨酸为起始原料，经酯化、选择还原和酯化合成反，反-2，4-己二烯醛醋酸酯。山梨酸甲酯的还原反应以氢化铝锂为还原剂，加入无水三氯化铝减弱还原活性，保护共轭双键，收率约79％，高于文献报道。本文方法操作简单易行，对溶剂和设备无特殊要求。
이산리산위기시원료，경지화、선택환원화지화합성반，반-2，4-기이희철작산지。산리산갑지적환원반응이경화려리위환원제，가입무수삼록화려감약환원활성，보호공액쌍건，수솔약79％，고우문헌보도。본문방법조작간단역행，대용제화설비무특수요구。
Trans, trans-2,4- hexadienyl acetate was synthesized using sorbic acid as starting material by esterification, selective reduction and esterification. For methyl sorbate＇ s reduction, with lithium aluminium hydride and adding aluminum chloride anhydrous can protect conjugated double bonds, and the yield was about 79%, higher than that reported in the literature. This method was simple and easy in operation, and no special requirements on the solvent and equipment.