CAJ | 학술논문

研究以丙酮为原料液相法合成异佛尔酮的液相缩合反应动力学。考察了以氢氧化钠为催化剂时,催化剂浓度、压力、温度、反应时间对反应的影响,结果表明该反应温度215～220℃、丙酮与水质量比3∶1、催化剂用量0.13 mol NaOH、压力3.8～4.5 MPa下反应3 h为最优反应条件。
연구이병동위원료액상법합성이불이동적액상축합반응동역학。고찰료이경양화납위최화제시,최화제농도、압력、온도、반응시간대반응적영향,결과표명해반응온도215～220℃、병동여수질량비3∶1、최화제용량0.13 mol NaOH、압력3.8～4.5 MPa하반응3 h위최우반응조건。
The liquid condensation reaction kinetics of isophorone synthesis using acetone as raw materials was studied.The influence of catalyst concentration,pressure,temperature and other factors on the reaction was investigated by NaOH as catalysts.It was found that under the optimum conditions of reaction temperature 215~225 ℃,the mass ratio of acetone and water was 3：1,0.13 mol NaOH,pressure 3.8~4.5 MPa,and 3 h,respectively.