CAJ | 학술논문

金属有机配位聚合物(MOCPs)具有纳米多孔的特殊结构,且结构具有可设计性,通过MOCPs活性位点与客体分子的包结作用能够选择性地包结多种客体分子,表现出特有的分子识别能力.MOCPs作为一种新型多孔材料在择形及手性催化、吸附分离、气体储存、分子识别与传感、生物模拟、微反应器等研究应用方面具有诱人的潜力.综述了MOCPs的设计、合成及主-客体相互作用方式,并展望了这种聚合物的应用前景.
금속유궤배위취합물(MOCPs)구유납미다공적특수결구,차결구구유가설계성,통과MOCPs활성위점여객체분자적포결작용능구선택성지포결다충객체분자,표현출특유적분자식별능력.MOCPs작위일충신형다공재료재택형급수성최화、흡부분리、기체저존、분자식별여전감、생물모의、미반응기등연구응용방면구유유인적잠력.종술료MOCPs적설계、합성급주-객체상호작용방식,병전망료저충취합물적응용전경.
The metal-organic coordination polymers(MOCPs)possess special nano-porons and designed struc-tares.These materials exhibit the capacity of molecular recognition and can incluse a variety of guest molecules selec-tively by the special interaction of MOCPs'active point with guest molecular.As a novel nano-porous material,they have attractive potential applications at the shape-selective,chiral catalysis,adsorption separation,gas storage,mo-lecular recognition and sensing,biological simulation,micro-reactor and so on.The research progress in the design,synthesis and the interaction behavior in host-guest complex of MOCPs have been reviewed in this paper.In addition,the prospect of MOCPs is also presented.