波谱学杂志
波譜學雜誌
파보학잡지
CHINESE JOURNAL OF MAGNETIC RESONANCE
1999年
3期
219-224
,共6页
张铭龙%崔育新%刘雪辉%李敬光%马灵台%张礼和
張銘龍%崔育新%劉雪輝%李敬光%馬靈檯%張禮和
장명룡%최육신%류설휘%리경광%마령태%장례화
Grignard亲和加成%绝对构型%二维核磁共振%计算机分子模拟
Grignard親和加成%絕對構型%二維覈磁共振%計算機分子模擬
Grignard친화가성%절대구형%이유핵자공진%계산궤분자모의
Grignard nucleophilic addition%Absolute configuration%2D NMR spectroscopy%Computational optimizing
通过对相应呋喃糖进行Grignard亲和加成合成了苯基及苄基取代呋喃糖.所得主要产物的结构和绝对构型通过二维核磁共振进行了研究.其结果通过计算机分子模拟优化,并进行了比较和确认.
通過對相應呋喃糖進行Grignard親和加成閤成瞭苯基及芐基取代呋喃糖.所得主要產物的結構和絕對構型通過二維覈磁共振進行瞭研究.其結果通過計算機分子模擬優化,併進行瞭比較和確認.
통과대상응부남당진행Grignard친화가성합성료분기급변기취대부남당.소득주요산물적결구화절대구형통과이유핵자공진진행료연구.기결과통과계산궤분자모의우화,병진행료비교화학인.
Phenyl and benzyl furanoses have been prepared stereoselectively by Grignard nucleophilic addition to their correspondent furanoses. Their structures and absolute configurations were studied and described by measuring the two-dimensional NMR spectroscopy. The results have been compared and confirmed by computational optimizing model data.
