无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2011年
3期
397-402
,共6页
赵率%郑明涛%谢春林%贺文启%易观贵%刘应亮
趙率%鄭明濤%謝春林%賀文啟%易觀貴%劉應亮
조솔%정명도%사춘림%하문계%역관귀%류응량
非晶态碳纳米管%热分解%正硅酸乙酯
非晶態碳納米管%熱分解%正硅痠乙酯
비정태탄납미관%열분해%정규산을지
amorphous carbon nanotubes%thermolysis%tetraethoxysilane
以正硅酸乙酯为碳源,采用简易热分解法,在无催化剂的条件下合成了竹节状非晶态碳纳米管.运用扫描电镜(SEM)和透射电镜(TEM)对样品进行表征,结果表明竹节状非晶态碳纳米管长几个微米,其外径和内径分别是30~40 nm和8~15 nm.该方法在无催化剂条件下制备出非晶态碳纳米管,对科学研究有着重要的意义和潜在的应用前景.
以正硅痠乙酯為碳源,採用簡易熱分解法,在無催化劑的條件下閤成瞭竹節狀非晶態碳納米管.運用掃描電鏡(SEM)和透射電鏡(TEM)對樣品進行錶徵,結果錶明竹節狀非晶態碳納米管長幾箇微米,其外徑和內徑分彆是30~40 nm和8~15 nm.該方法在無催化劑條件下製備齣非晶態碳納米管,對科學研究有著重要的意義和潛在的應用前景.
이정규산을지위탄원,채용간역열분해법,재무최화제적조건하합성료죽절상비정태탄납미관.운용소묘전경(SEM)화투사전경(TEM)대양품진행표정,결과표명죽절상비정태탄납미관장궤개미미,기외경화내경분별시30~40 nm화8~15 nm.해방법재무최화제조건하제비출비정태탄납미관,대과학연구유착중요적의의화잠재적응용전경.
A facile thermolysis route for the synthesis of amorphous carbon nanotubes (ACNTs) with bamboo-like morphology is presented, in which tetraethoxysilane is employed as carbon precursor. SEM and TEM results show that the obtained ACNTs exhibit a compartmentalized bamboo-like structure with an average outer diameter of about 30~40 nm and inner diameter of about 8~15 nm and several micrometers in length. The free of metal catalysts yields ACNTs, which is important for some fundamental scientific studies and also for promising applications.