无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2006年
7期
1285-1288
,共4页
赵琦华%王丽%王昆淼%方瑞斌
趙琦華%王麗%王昆淼%方瑞斌
조기화%왕려%왕곤묘%방서빈
Cd(Ⅱ)%晶体结构%dafo%SCN-桥联
Cd(Ⅱ)%晶體結構%dafo%SCN-橋聯
Cd(Ⅱ)%정체결구%dafo%SCN-교련
cadmium(Ⅱ)%crystal structure%4,5-diazafluoren-9-one%thiocyanato bridging
A new one-dimensional compound [Cd(dafo)(SCN)2]n (dafo=4,5-diazafluoren-9-one) has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca with a=1.708 6(5), b=1.303 6(4), c=2.592 6(8) nm, V=5.775(3) nm3, and Z=16. The crystal structure revealed that the structure of [Cd(dafo)(SCN)2]n featuresμ-1,3-thiocyante bridges and 1D chains. It consists of octahedrally coordinated Cd atoms. Both Cd(1) and Cd(2) are surrounded by two nitrogen atoms from dafo, two S atoms and two N atoms from two di-μ-1,3 thiocyanato bridges. CCDC: 251185.
