发光学报
髮光學報
발광학보
CHINESE JOURNAL OF LUMINESCENCE
2009年
6期
818-823
,共6页
王香%马旭梁%封雪%郑玉峰
王香%馬旭樑%封雪%鄭玉峰
왕향%마욱량%봉설%정옥봉
ZnSe,ZnS%量子点%合成%光致发光
ZnSe,ZnS%量子點%閤成%光緻髮光
ZnSe,ZnS%양자점%합성%광치발광
ZnSe,ZnS%quantum dots%synthesis%photoluminescence
采用改进后的合成方法,以Se和ZnO粉末为原料,在十六胺(HDA)、月桂酸(LA)和三辛基膦(TOP)有机溶剂体系中合成了胶体ZnSe和ZnS量子点.主要研究了溶剂配比、反应温度及生长时间对ZnSe量子点粒径和光学性质的影响.结果表明:制得的ZnSe和ZnS量子点均是纤锌矿型结构,且具有较好的尺寸均匀性、分散性及荧光特性.粒子直径可控制在4.5~8 nm范围内.采用参数n(ZnO):n(HDA):n(LA)=1:2.1:5.2,c(TOPSe)=1 mol/L,在280 ℃成核,240 ℃生长条件下合成的ZnSe量子点具有最佳的尺寸范围,并且随着生长时间的延长,粒径变大,荧光发射峰明显红移.
採用改進後的閤成方法,以Se和ZnO粉末為原料,在十六胺(HDA)、月桂痠(LA)和三辛基膦(TOP)有機溶劑體繫中閤成瞭膠體ZnSe和ZnS量子點.主要研究瞭溶劑配比、反應溫度及生長時間對ZnSe量子點粒徑和光學性質的影響.結果錶明:製得的ZnSe和ZnS量子點均是纖鋅礦型結構,且具有較好的呎吋均勻性、分散性及熒光特性.粒子直徑可控製在4.5~8 nm範圍內.採用參數n(ZnO):n(HDA):n(LA)=1:2.1:5.2,c(TOPSe)=1 mol/L,在280 ℃成覈,240 ℃生長條件下閤成的ZnSe量子點具有最佳的呎吋範圍,併且隨著生長時間的延長,粒徑變大,熒光髮射峰明顯紅移.
채용개진후적합성방법,이Se화ZnO분말위원료,재십륙알(HDA)、월계산(LA)화삼신기련(TOP)유궤용제체계중합성료효체ZnSe화ZnS양자점.주요연구료용제배비、반응온도급생장시간대ZnSe양자점립경화광학성질적영향.결과표명:제득적ZnSe화ZnS양자점균시섬자광형결구,차구유교호적척촌균균성、분산성급형광특성.입자직경가공제재4.5~8 nm범위내.채용삼수n(ZnO):n(HDA):n(LA)=1:2.1:5.2,c(TOPSe)=1 mol/L,재280 ℃성핵,240 ℃생장조건하합성적ZnSe양자점구유최가적척촌범위,병차수착생장시간적연장,립경변대,형광발사봉명현홍이.
Adopting improved metal-organic "Green method", colloidal ZnSe, ZnS quantum dots (QDs) were prepared using cheap and low toxic zinc oxide (ZnO) in an organic solvent system of 1-hexadecylamine (HDA), lauric acid (LA) and tri-n-octylphosphine (TOP). The effects of solvents ratio, reaction temperature and growth time on the QD size and photoluminescence properties of ZnSe and ZnS QDs were studied. The results showed that ZnSe and ZnS QDs exhibit the wurtzite structure, good uniformity, dispersity and fluorescent characteristics. The average diameters are in the range of 4.5~8 nm. Choosing the optimal parameters, n(ZnO):n(HDA):n(LA)=1:2.1:5.2, c_(TOPSe)=1 mol/L, ZnSe QDs with large distributioin range of the size were obtained under the condition of nucleation at 280 ℃ and growth at 240 ℃. With increasing the growth time, the QD size become larger and the emission peak obviously shifts to red.