CAJ | 학술논문

以过渡金属铼为中心金属离子,合成了2-(2-吡啶)苯并咪唑(HL1)和2,6-二(苯并咪唑)吡啶(HL2)配合物.该配合物荧光量子产率高、化学性质稳定,在固体状态下,最大发射峰分别是543 nm、577 nm,处在绿光和黄光区.其发光基理是基态金属离子电荷向激发态配体跃迁(MLCT),属于金属离子与配体间的dπ→π~*(L)的跃迁发光.
이과도금속래위중심금속리자,합성료2-(2-필정)분병미서(HL1)화2,6-이(분병미서)필정(HL2)배합물.해배합물형광양자산솔고、화학성질은정,재고체상태하,최대발사봉분별시543 nm、577 nm,처재록광화황광구.기발광기리시기태금속리자전하향격발태배체약천(MLCT),속우금속리자여배체간적dπ→π~*(L)적약천발광.
A kind of new material consisting of Re centralion and benzimidazole ligands had been deve loped.These novel luminescent complexes were synthesized.In the solid state,these complexes 1,and 2 have an emission maximum at 543,577 nm,respectively.They display yellow,green luminescence and have high luminescence quantum efficiency.The luminescent properties of Re (I) pyridyl-imidazole complex was also investigated,the assignment of emission was notable metal to ligand charge transfer (MLCT) process upon dπ→π~*(L) transition.