CAJ | 학술논문

为了揭示有机酸对长江三角洲区域降水酸化的影响,2008年在浙江临安区域大气本底站采集了35场降水的样本,用离子色谱梯度淋洗方法测定有机酸浓度.结果表明,甲酸、乙酸、甲磺酸、乙二酸、丙二酸、丁二酸、戊二酸均有不同程度检出,一元有机酸中甲酸和乙酸在每场降水中均有检出;二元有机酸中,乙二酸和丁二酸检出率很高,其他有机酸检出率较低.甲酸、乙酸和乙二酸约占检测到的总有机酸的89%,其中甲酸和乙酸占总有机酸的80%,约占阴离子总量的13%;甲酸,乙酸、总有机酸的浓度及其在阴离子总量中所占比例都远高于我国北京、深圳等城市,有机酸对长江三角洲大气背景区降水化学的影响比城市地区显著.另外,生长季节降水中有机酸浓度高于非生长季节.表明植被排放的有机酸是长江三角洲大气背景区降水中有机酸的重要来源.
위료게시유궤산대장강삼각주구역강수산화적영향,2008년재절강림안구역대기본저참채집료35장강수적양본,용리자색보제도림세방법측정유궤산농도.결과표명,갑산、을산、갑광산、을이산、병이산、정이산、무이산균유불동정도검출,일원유궤산중갑산화을산재매장강수중균유검출;이원유궤산중,을이산화정이산검출솔흔고,기타유궤산검출솔교저.갑산、을산화을이산약점검측도적총유궤산적89%,기중갑산화을산점총유궤산적80%,약점음리자총량적13%;갑산,을산、총유궤산적농도급기재음리자총량중소점비례도원고우아국북경、심수등성시,유궤산대장강삼각주대기배경구강수화학적영향비성시지구현저.령외,생장계절강수중유궤산농도고우비생장계절.표명식피배방적유궤산시장강삼각주대기배경구강수중유궤산적중요래원.
In order to investigate the impact of organic acids on acid rain in the background region of the Yangtze River Delta, 35 rainwater samples were collected during 2008 in the Lin'an Regional Background Air Station and analyzed for organic acids using ion chromatography. In result, formic, acetic, methanesuifonic, oxalic, malonic, succinic and glutaric acids were detected notably. Formic, acetic and oxalic acids were the most abundant organic acids, and the sum of their concentrations averagely accounted for 89% of the total detected organic acids and 13% of the total anions, respectively. Concentrations of formic and acetic acids, the total organic acids and their fractions in the total anions were much higher than those in the urban areas of Beijing and Shenzhen, which indicated that organic acids influenced more on rainwater acidification in the Yangtze River Delta. In the growing seasons, i.e., spring and summer, concentrations of organic acids were found significantly higher than those in the non-growing seasons, implying vegetation emissions are a potentially important source of organic acids in the rainwater.