CAJ | 학술논문

采用新型氧化剂DMF-NO_2对缩醛(酮)进行了选择性氧化研究.结果表明:在较温和的条件下,缩醛(酮)可被高效氧化裂解为相应的醛、酮,反应具有一定的选择性,同时避免了NO_2对大气的污染,从而为羰基的脱保护和NO_2废气治理与利用提供了一条新途径.
채용신형양화제DMF-NO_2대축철(동)진행료선택성양화연구.결과표명:재교온화적조건하,축철(동)가피고효양화렬해위상응적철、동,반응구유일정적선택성,동시피면료NO_2대대기적오염,종이위탄기적탈보호화NO_2폐기치리여이용제공료일조신도경.
DMF-NO_2,which was formed by using DMF as the absorbent to absorb NO_2,was used as the oxidant to study the oxidative cleavage of acetals (ketals).The test results showed that DMF-NO_2 could convert acetals (ketals) to corresponding aldehydes and ketones selectively in high yields,which provided a new method for the cleavage of acetals (ketals) and for the treatment and utilization of waste NO_2 gas.