一维双链镉(Ⅱ)配合物[Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n的合成与晶体结构
일유쌍련력(Ⅱ)배합물[Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n적합성여정체결구
Synthesis and Crystal Structure of a Double Chain Complex [Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2010年 9期 1703-1706 ,共4页

    马运声%唐晓艳%袁荣鑫

    마운성%당효염%원영흠

    镉配合物%吡啶基二膦酸%晶体结构 鎘配閤物%吡啶基二膦痠%晶體結構
    력배합물%필정기이련산%정체결구
    cadmium complex%pyridyl-diphosphonate%crystal structure


    A new cadmium complex [Cd(C5H5N)CH2C(OH)(PO3)(PO3H)·3H2O]n ((C5H4N)CH2C(OH)(PO3H2)2=1-hydroxy-2-(2-pyndyl)ethylidene-1,1-diphosphonate acid) has been synthesized under hydrothermal conditions.Single crystal structure determination reveals that the compound has a ladder-like chain structure in which the edgeshared {CdO6} octahedra are linked by {CPO3} tetrahedra through comer-sharing.The chains of {Cd(C5H5N)CH2C (OH)(PO3)(PO3H)}n are linked by inter-chain hydrogen bonds,forming a supramolecular layer.
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