扬州职业大学学报
颺州職業大學學報
양주직업대학학보
JOURNAL OF YANGZHOU POLYTECHNIC COLLEGE
2011年
4期
49-52
,共4页
普鲁士蓝%类普鲁士蓝%碳糊电极%过氧化氢%铁氰化钴
普魯士藍%類普魯士藍%碳糊電極%過氧化氫%鐵氰化鈷
보로사람%류보로사람%탄호전겁%과양화경%철청화고
the Prussia blue%analogous Prussia blue%carbon paste electrode%hydrogen peroxide%iron cyani- ding cobalt
研究了铁、钴、镍、铜与铋形成的普鲁士蓝及类普鲁士蓝的制备,并将它们用于修饰碳糊电极得到电化学传感器。研究表明:铁氰化钴修饰碳糊电极对H2O2有明显的电催化作用,将它用于H2O2的测定取得较好的结果,测定的线性范围为5.34×10^-6~5.34×10^-4mol·L^-1。该电极具有灵敏度高、稳定性和重现性好等特点。
研究瞭鐵、鈷、鎳、銅與鉍形成的普魯士藍及類普魯士藍的製備,併將它們用于脩飾碳糊電極得到電化學傳感器。研究錶明:鐵氰化鈷脩飾碳糊電極對H2O2有明顯的電催化作用,將它用于H2O2的測定取得較好的結果,測定的線性範圍為5.34×10^-6~5.34×10^-4mol·L^-1。該電極具有靈敏度高、穩定性和重現性好等特點。
연구료철、고、얼、동여필형성적보로사람급류보로사람적제비,병장타문용우수식탄호전겁득도전화학전감기。연구표명:철청화고수식탄호전겁대H2O2유명현적전최화작용,장타용우H2O2적측정취득교호적결과,측정적선성범위위5.34×10^-6~5.34×10^-4mol·L^-1。해전겁구유령민도고、은정성화중현성호등특점。
In this paper, the preparation of iron, cobalt, nickel, copper and bismuth formation of the Prussia blue and analogous Prussia blue had been researched. The Prussia blue and analogous Prussia blue also be applied to modify the carbon paste electrode and results showed that the electrode modified by the cobalt formation of the Prussia blue obviously was electrocatalytie to H2O2. It was applied to detect H2O2 and the good results was obtained. The detection of line range was 5.34×10^-6~5.34×10^-4mol·L^-1 and the electrode had characteristics such as high sensitivity, good stability and repeatability.